88142-51-2

Upstream product

• 59057-30-6 (1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol 
• 53282-28-3 [(2E,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienyl]triphenylphosphonium chloride 
• 103410-76-0 (E)-3-Ethyl-2-buten-1,4-dial-1-diethylacetal 
• 1220-77-5 (3E,7E)-6-methyl-8-(2,6,6-trimethylcyclohex-1-enyl)octa-3,5,7-trien-2-one 
• 106140-76-5 methyl 20-nor-13-ethylretinoate 
• 106140-75-4 methyl 20-nor-13,14-didehydroretinoate 
• 106140-74-3 3-methyl-1-(2,6,6-trimethylcyclohexen-1-yl)-1,3,5-octatrien-7-yne 

Downstream Products

• 106140-77-6 methyl 20-nor-13-tert-butylretinoate 
• 106140-78-7 9-cis,13-cis-20-nor-13-tert-butylretinal 
• 106140-78-7 13-cis-20-nor-13-tert-butylretinal 
• 113729-95-6 (2E,4E,6E,8E)-3-tert-Butyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraen-1-ol 

Relevant academic research and scientific papers

Retinoids. 6. Preparation of alkyl- and trimethylsilyl-substituted retinoids via conjugate addition of cuprates to acetylenic esters

Five retinoids bearing the ethyl, tert-butyl, and trimethylsilyl groups in the 9-position of retinal and the ethyl and tert-butyl groups in the 13-position have been synthesized. The key step of the syntheses involves the conjugate addition of lithium die

Retinoids and Carotenoids, V.- Synthesis of Modified Retinals

The syntheses of 13-demethyl-13-ethyl-, 13-demethyl-13-propyl-, 13-demethyl-, 13-demethyl-14-methyl-, and 14-methylretinal are described.The UV spectra of some geometric isomers of these compounds are discussed.