88151-67-1Relevant academic research and scientific papers
N-heterocyclic carbenes mediated cyano-phosphorylation of ketones
He, Lin,Zhang, Jing,Fan, Ye-Cheng,Du, Guang-Fen,Zhang, Jie,Dai, Bin
, p. 5861 - 5864 (2013)
Cyanation-O-protection reaction of ketones with different cyanide sources catalyzed by N-heterocyclic carbenes is reported. Under the catalysis of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, various ketones coupled with diethyl cyanophosphonate to p
CYANOPHOSPHORYLATION OF KETONES AND ALDEHYDES USING DIETHYL PHOSPHOROCYANIDATE (DEPC)
Harusawa, Shinya,Yoneda, Ryuji,Kurihara, Takushi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 2932 - 2935 (2007/10/02)
A novel one-pot and high-yield cyanophosphorylation of carbony compounds is achieved by treatment of ketones or aldehydes with diethyl phosphorocyanidate (DEPC) in the presence of a catalytic amount of lithium diisopropylamide in tetrahydrofuran.KEYWORDS
