88152-23-2Relevant academic research and scientific papers
Preparation of Monomeric Neutral or Anionic Tris(polyfluorophenyl)thallium(III) and of Anionic Heteronuclear Tris(polyfluorophenyl)thallium-Metal Carbonyl Complexes
Uson, Rafael,Laguna, Antonio,Abad, J. Antonio,Jesus, Ernesto de
, p. 1127 - 1130 (2007/10/02)
The complex (diox= 1,4-dioxan) has been prepared by the reaction of TlCl3 with LiR (R= 2,4,6-C6F3H2), or of with HBF4 (R= C6F5) and subsequent addition of dioxan.The displacement of dioxan by (a) neutral ligands leads to (L= OPPh3, pyridine, PPh3, or Ph2PCH2PPh2); (b) anionic ligands affords Q (+) or (+); X= Cl(-), CN(-), NO3(-), or CF3CO2(-)>; and (c) metal carbonylate gives Q (-) (cp= η-C5H5), (-), (-) or (-)>.
