88158-58-1

Basic information

• Product Name: 3-Buten-2-ol, 4-(2,4,6-trimethylphenyl)-, acetate, (E)-
• CAS NO: 88158-58-1
• Molecular Formula: C15H20O2
• Molecular Weight: 232.323
• Mol File: 88158-58-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-ol, 4-(2,4,6-trimethylphenyl)-, acetate, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-ol, 4-(2,4,6-trimethylphenyl)-, acetate, (E)-(88158-58-1)
• EPA Substance Registry System: 3-Buten-2-ol, 4-(2,4,6-trimethylphenyl)-, acetate, (E)-(88158-58-1)

Safety Data

• Hazardous Substances Data: 88158-58-1(Hazardous Substances Data)

Upstream product

• 84473-23-4 trans-α-methyl-γ-mesitylallyl alcohol 
• 108-24-7 acetic anhydride 

Downstream Products

• 16204-62-9 (E)-1-(2,4,6-trimethylphenyl)-3-methyl-1-butene 
• 84473-26-7 (Z)-4-(2,4,6-trimethylphenyl)-2-pentene 
• 84473-25-6 (E)-4-(2,4,6-trimethylphenyl)-2-pentene 

Relevant articles and documents

Alkylation of Allylic Derivatives. 8. Regio- and Stereochemistry of Alkylation of Allylic Carboxylates with Lithium Methylcyanocuprate

Alkylation of 5-methyl-2-cyclohexenyl acetate (1-OAc) with lithium methylcyanocuprate (LiCu(CN)Me) is regiospecific (>90 percent excess γ-alkylation) and sterospecific (>95 percent anti alkylation).In the bicyclooct-3-en-2-yl system (3), alkylation is stereoselective (both isomers give exo alkylation) and regiospecific (excess γ-alkylation).Alkylation of trans-α-methyl-γ-mesitylallyl acetate (8-OAc) with LiCu(CN)Me gives 57 percent α- and 43 percent γ-alkylation as compared to >97 percent α-alkylation with LiCuMe2.Mechanistic implications are discussed.