88166-01-2Relevant academic research and scientific papers
CONFIGURATIONAL STABILITY OF ALLENIC ANIONS, uSE OF A VITAMIN D DERIVED CD FRAGMENT AS A STEREOCHEMICAL PROBE AND THE STEREOSELECTIVE SYNTHESIS OF PRECURSORS
Kruchten, Eugene M. G. A. van,Haces, Alberto,Okamura, William H.
, p. 3939 - 3942 (1983)
Metallation (n-BuLi, t-BuOK, THF) followed by quenching (DCl, D2O) of (S)-allenes 4a-c occurs primarily with retention of configuration, whereas that of (R)-allenes 4d-e occurs mainly with inversion; the allenes 4 were prepared from related propargyl alco
