88218-84-2

Upstream product

• 5285-87-0 phenyl thiocyanate 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 19521-13-2 α,β-dibromo-β-phenylpropionitrile 
• 1885-38-7 cinnamic nitrile 
• 91164-91-9 3-((Z)-2-Cyano-1-phenyl-vinyl)-1-methyl-3H-imidazol-1-ium; iodide 
• 108-98-5 thiophenol 
• 80887-98-5 (Z)-3-Imidazol-1-yl-3-phenyl-acrylonitrile 

Relevant academic research and scientific papers

From 1,2-difunctionalisation to cyanide-transfer cascades-Pd-catalysed cyanosulfenylation of internal (oligo)alkynes

Internal alkynes substituted by aliphatic or aromatic moieties or by heteroatoms were converted into sulphur-substituted acrylonitrile derivatives. Key is the use of Pd catalysis, which allows the addition of aromatic and aliphatic thiocyanates in an intra- A nd intermolecular manner. Substrates with several alkyne units underwent further carbopalladation steps after the initial thiopalladation step, thus generating in a cascade-like fashion an oligoene unit with sulphur at one terminus and the cyano group at the other.

The Compounds Related to 3-(1-Imidazolyl)-2-alken-1-ones. Preparation and Reactions

Compounds related to 3-(1-imidazolyl)-2-alken-1-ones, 3-(1-imidazolyl)-2-alkenoic acid derivatives and 2-alken-1-ones having heterocycles on the C-3 carbon were prepared.The reaction of nucleophiles with these compounds was also discussed.