882182-83-4Relevant academic research and scientific papers
Cis-selective preparation of 2,2-difluorocyclopropyl ketones via non-metal hydride reduction of 2,2-difluorocyclopropenyl ketones
Zheng, Zhaoyun,Dolbier Jr., William R.
, p. 119 - 124 (2013/04/24)
Diastereoselective reduction of gem-difluorocyclopropenyl ketones was accomplished by their Br?nsted acid catalyzed reactions with the non-metal based hydride transfer reagent, Hantzsch ester (diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate) (H
Difluorocarbene chemistry: Synthesis of gem-difluorocyclopropenyl ketones and gem-difluorinated dihydrofurans
Cheng, Zhan-Ling,Chen, Qing-Yun
, p. 478 - 480 (2007/10/03)
The cycloaddition reactions of difluorocarbene, generated by the decomposition of FSO2CF2CO2SiMe3, with α,β-acetylenic ketones give gem-difluorocyclopropenyl ketones in good yields. Treatment of these gem-difluo
