88235-58-9Relevant articles and documents
Evidence for Thermal 3,5-Sigmatropy of 7-Vinylcaradienes
Battye, Peter J.,Jones, David W.
, p. 1807 - 1808 (1986)
7-Phenyl-7-vinylcycloheptatrienes rearrange via their endo-norcaradiene valence tautomers (1; a-d) to give the dihydroindenes (2; a-d) and the Cope products (3; a-c); dihydroindene formation is stereospecific, and strongly inhibited in the benzonorcaradie
THERMAL REACTION OF 2,3-DIAZATETRACYCLO4,11.06,8>UNDECA-2,9-DIENES: THE NITROGEN EXTRUSION AND THE MASKED HOMODIENYL-1,5-HYDROGEN SHIFT
Ohba, Yoshihiro,Kumagai, Tsutomu,Mukai, Toshio
, p. 1361 - 1364 (2007/10/02)
Thermolyses of the title compounds produce three kinds of products which are derived from nitrogen extrusion and 1,5-hydrogen shifts.The reaction mechanism is discussed in connection with the thermal behavior of bicyclononatriene.