882426-12-2Relevant articles and documents
Intramolecular bromo-amination of 1,4-cyclohexadiene aminal: One-pot discrimination of two olefins and concise asymmetric synthesis of (-)-γ-lycorane
Fujioka, Hiromichi,Murai, Kenichi,Ohba, Yusuke,Hirose, Hideki,Kita, Yasuyuki
, p. 832 - 834 (2008/02/08)
The reaction of cyclohexa-2,5-dienyl-1-methylaldehyde and optically pure 1,2-diaryl-1,2-diamine followed by intramolecular bromo-amination produced a one-pot discrimination of two olefins in the cyclohexane system, which was used for the asymmetric synthesis of (-)-γ-lycorane. The Royal Society of Chemistry 2006.