88274-91-3

Usage

Unsaturated alcohol

Alkynol
Contains both a triple bond and a hydroxyl group in its chemical structure.

Classification

Fatty alcohol
Commonly found in biological membranes and lipid structures.

Usage

Building block in synthetic and organic chemistry
Used for the synthesis of various compounds.

(E)designation

Trans-configuration
Indicates that the double bond in the compound has the two highest priority groups on opposite sides.

Upstream product

• 78617-57-9 2-[((E)-Hexadec-13-en-11-ynyl)oxy]-tetrahydro-pyran 
• 112-47-0 1,10-Decanediol 
• 53463-68-6 1-bromo-10-decanol 
• 105-31-7 1-hexyn-3-ol 
• 51795-88-1 1-bromo-10-(tetrahydropyranyloxy)decane 
• 83375-28-4 1,13-bis<(tetrahydro-2-pyranyl)oxy>-11-hexadecyne 
• 80863-16-7 10-iodo-1-<(tetrahydro-2-pyranyl)oxy>decane 
• 829-82-3 3-<(tetrahydro-2-pyranyl)oxy>-1-hexyne 
• 83375-29-5 11-hexadecyne-1,13-diol 

Relevant academic research and scientific papers

A STEREOSELECTIVE SYNTHESIS OF (Z)-13-HEXADECEN-11-YNYL ACETATE, THE SEX PHEROMONE OF Thaumetopoea pityocampa (LEPIDOPTERA, NOTODONTIDAE)

(Z)-13-Hexadecen-11-ynyl acetate, 1, the sex pheromone of Thaumetopoea pityocampa, has been synthesized stereospecifically, starting from anion of 3--1-hexyne, 8, which was alkylated with 10-iodo-1-decane; the intermediate diol 2, obtained upon removal of the protecting groups was stereoselectively dehydrated with KHSO4.

SYNTHESIS OF THE TWO ISOMERS OF THE POTENTIAL SEX PHEROMONE OF THAUMETOPOEA PITYOCAMPA (LEPIDOPTERA, NOTODONTIDAE) AND RELATED MODEL COMPOUNDS

The synthesis of the major component of the sex pheromone secretion of the processionary moth, Thaumetopoea pityocampa (Denis and Schiff.) (Lepidoptera, Notodontidae), (Z)-13-hexadecen-11-ynyl acetate (1), the corresponding (E)-isomer (2) and the four structurally related model compounds (Z/E,Z,Z)-5,9,13-hexadecatrienyl acetate (3), (Z/E,Z,Z)-3,7,11-hexadecatrienyl acetate (4), (Z/E,E,Z)-7,9,13-hexadecatrienyl acetate (5) and (Z)-7-hexadecen-5-ynyl acetate (6) is described.