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88275-87-0

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88275-87-0 Usage

General Description

3-Bromo-2-methoxybenzaldehyde is a chemical compound with the molecular formula C8H7BrO2. It is a pale yellow solid with a molecular weight of 209.05 g/mol. The compound is commonly used as an intermediate in the synthesis of pharmaceuticals, dyes, and other organic compounds. It is also used in organic reactions for the preparation of various derivatives. 3-Bromo-2-methoxybenzaldehyde is a potent and versatile building block in organic chemistry, and its derivatives have a wide range of applications in the industrial and pharmaceutical fields.

Check Digit Verification of cas no

The CAS Registry Mumber 88275-87-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,2,7 and 5 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 88275-87:
(7*8)+(6*8)+(5*2)+(4*7)+(3*5)+(2*8)+(1*7)=180
180 % 10 = 0
So 88275-87-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H7BrO2/c1-11-8-6(5-10)3-2-4-7(8)9/h2-5H,1H3

88275-87-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Bromo-2-methoxybenzaldehyde

1.2 Other means of identification

Product number -
Other names 3-bromo-o-anisaldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:88275-87-0 SDS

88275-87-0Relevant articles and documents

First Total Synthesis of 7-Isovaleryloxy-8-methoxygirinimbine

Brütting, Christian,Schmidt, Arndt W.,Kataeva, Olga,Kn?lker, Hans-Joachim

, p. 2516 - 2522 (2018)

We describe the first total synthesis of the pyrano[3,2- a ]carbazole alkaloid 7-isovaleryloxy-8-methoxygirinimbine, using a palladium(II)-catalyzed double C-H-bond activation for construction of the carbazole framework and a phenylboronic acid catalyzed

Redox-Neutral Coupling between Two C(sp3)?H Bonds Enabled by 1,4-Palladium Shift for the Synthesis of Fused Heterocycles

Rocaboy, Ronan,Anastasiou, Ioannis,Baudoin, Olivier

supporting information, p. 14625 - 14628 (2019/09/16)

The intramolecular coupling of two C(sp3)?H bonds to forge a C(sp3)?C(sp3) bond is enabled by 1,4-Pd shift from a trisubstituted aryl bromide. Contrary to most C(sp3)?C(sp3) cross-dehydrogenative couplings, this reaction operates under redox-neutral conditions, with the C?Br bond acting as an internal oxidant. Furthermore, it allows the coupling between two moderately acidic primary or secondary C?H bonds, which are adjacent to an oxygen or nitrogen atom on one side, and benzylic or adjacent to a carbonyl group on the other side. A variety of valuable fused heterocycles were obtained from easily accessible ortho-bromophenol and aniline precursors. The second C?H bond cleavage was successfully replaced with carbonyl insertion to generate other types of C(sp3)-C(sp3) bonds.

A Mild meta-Selective C–H Alkylation of Catechol Mono-Ethers

Vitaku, Edon,Njardarson, Jon T.

supporting information, p. 3679 - 3683 (2016/08/16)

Catechol mono-ethers are an important class of phenols. They are found in a number of pharmaceuticals, flavoring agents, perfumes, and are used for the preparation of numerous drugs. Herein, we report a mild meta-selective C–H alkylation of these phenols, which is enabled by a cascade of oxidative dearomatization – radical addition – rearomatization process. The method is compatible with reactive functional groups on the parent arenol, such as olefins and halides. Primary, secondary, and teriary alkyl groups can be used, the source of which is most commonly an alkylborane. This process is operationally simple, does not require heating and generally proceeds in good yields.

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