882788-93-4

Basic information

• Product Name: N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline
• Synonyms: N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline
• CAS NO: 882788-93-4
• Molecular Weight: 227.349
• Mol File: 882788-93-4.mol

Chemical Properties

• CAS DataBase Reference: N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline(882788-93-4)
• EPA Substance Registry System: N,N-diallyl-2-(2-methylprop-2-en-1-yl)aniline(882788-93-4)

Safety Data

• Hazardous Substances Data: 882788-93-4(Hazardous Substances Data)

Upstream product

• 615-43-0 2-iodophenylamine 
• 73396-92-6 2-iodo-N,N-diallylaniline 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 722-97-4 5,5-diallyl-1,3-dimethyl-pyrimidine-2,4,6-trione 
• 59816-87-4 2-(2-methylprop-2-en-1-yl)aniline 
• 1627211-09-9 C₁₆H₁₆N₂O₄S 
• 177763-17-6 4-methyl-N-[2-(2-methylallyl)phenyl]benzenesulfonamide 
• 1627210-78-9 C₁₇H₁₅N₃O₄S 
• 1627210-70-1 C₁₈H₁₇FN₂O₂S 
• 1627210-81-4 C₁₈H₁₈N₂O₂S 
• 1640995-83-0 C₁₇⁽¹³⁾CH₁₈N₂O₂S 
• 1627210-66-5 C₁₇H₁₅N₃O₄S 
• 1627210-80-3 C₁₈H₁₈N₂O₂S 
• 1573116-64-9 N-tert-butoxycarbonyl-N-[2-(2-methylprop-2-en-1-yl)phenyl]cyanamide 

Relevant articles and documents

Palladium(II)-catalyzed intramolecular tandem aminoalkylation via divergent C(sp3)-H functionalization

(Chemical Equation Presented) We have developed a Pd(II)-catalyzed oxidative tandem aminoalkylation via divergent C(sp3)-H functionalization, a ffording three- and five-membered-ring fused indolines in good yields under two optimized conditions, respectively. The mechanism studies have indicated that the benzylic C - H cleavage involved in the former transformation is the rate-determining step, while the cleavage of amide α-C - H in the latter is not. This is the first example of a Pd-catalyzed tandem reaction involving C(sp3)-H activation without the employment of prefunctionalized reagents (e.g., halogenated and boron reagents) and directing groups, representing a green and economic protocol for the construction of N-containing heterocycles.

Intramolecular aminocyanation of alkenes by N-CN bond cleavage

A metal-free, Lewis acid promoted intramolecular aminocyanation of alkenes was developed. B(C6F5)3 activates N-sulfonyl cyanamides, thus leading to a formal cleavage of the N-CN bonds in conjunction with vicinal addition o

Intramolecular aminocyanation of alkenes by cooperative palladium/boron catalysis

A cooperative palladium/triorganoboron catalyst to accomplish the intramolecular aminocyanation of alkenes through the cleavage of N-CN bonds is reported. 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene (Xantphos) is found to be crucial as a ligand for palladium to effectively catalyze the transformation with high chemo- and regioselectivity. A range of substituted indolines and pyrrolidines with both tetra- or trisubstituted carbon and cyano functionalities are readily furnished by the newly developed cyanofunctionalization reaction. A preliminary example of enantioselective aminocyanation is also described.

Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation

We have developed an efficient Pd(II)-catalyzed enantioselective oxidative tandem cyclization strategy using molecular oxygen as a green oxidant for the double 5-exo-trig cyclizations of N-(2-allylaryl) amides to afford a variety of indolines in good yiel