882854-67-3Relevant academic research and scientific papers
Facile generation of a strained cyclic vinyl cation by thermal solvolysis of cyclopent-1-enyl-λ3-bromanes
Miyamoto, Kazunori,Shiro, Motoo,Ochiai, Masahito
, p. 8931 - 8934 (2009)
Last of the cyclic vinyl cations: The simple solvolysis of cyclopent-1 -enyl-13-bromane efficiently generates the highly strained cyclopent-1 -enyl cation at room temperature (see scheme). The very high nucleofugality of the aryl-13-bromanyl groups are re
