882874-10-4Relevant academic research and scientific papers
Catalytic asymmetric desymmetrization of meso-diamide derivatives through enantioselective N-allylation with a chiral π-allyl Pd catalyst: Improvement and reversal of the enantioselectivity
Kitagawa, Osamu,Matsuo, Shinichi,Yotsumoto, Kanako,Taguchi, Takeo
, p. 2524 - 2527 (2006)
In the presence of the Trost ligands-Pd catalysts, N-monoallylation of bis(2,4,6-triisopropylbenzne)sulfonylamides derived from meio-1,2-diamines proceeds with good to excellent enantioselectivity (85-96% ee) to give asymmetric desymmetrization products.
