88288-59-9Relevant academic research and scientific papers
Selective catalytic synthesis of unsymmetrical ethers from the dehydrative etherification of two different alcohols
Kim, Junghwa,Lee, Dong-Hwan,Kalutharage, Nishantha,Yi, Chae S.
, p. 3881 - 3885 (2015/01/16)
The cationic ruthenium-hydride complex [(C6H6)(PCy3)(CO)RuH]+BF4- catalyzes selective etherification of two different alcohols to form unsymmetrically substituted ethers. The catalytic method exhibits a broad substrate scope while tolerating a range of heteroatom functional groups in forming unsymmetrical ethers, and it is successfully used to directly synthesize a number of highly functionalized chiral nonracemic ethers.
Silica-supported KHSO4: An efficient system for activation of aromatic terminal olefins
Das, Ram Nath,Sarma, Kuladip,Pathak, Madan Gopal,Goswami, Amrit
supporting information; experimental part, p. 2908 - 2912 (2011/02/25)
Potassium hydrogen sulfate adsorbed on chromatography-grade silica gel activates electron-rich aromatic terminal olefins towards nucleophilic attack at the benzylic position by alcohols. Temperature plays a crucial role and facilitates suppressing nucleophilic reaction in favor of dimerization of the terminal olefin. Georg Thieme Verlag Stuttgart - New York.
NBS-catalyzed hydroamination and hydroalkoxylation of activated styrenes
Talluri, Siva Kumar,Sudalai, Arumugam
, p. 855 - 857 (2007/10/03)
(Chemical Equation Presented) N-Bromosuccinimide efficiently catalyzes the hydroamination and hydroalkoxylation of activated styrenes using tosylamides, carbamates, and alcohols as the nucleophiles to afford amino and ether derivatives, respectively. Both
Reactivity-Selectivity in the Swern Oxidation of Alcohols Using Dimethyl Sulfoxide-Oxalyl Chloride
Marx, Michael,Tidwell, Thomas T.
, p. 788 - 793 (2007/10/02)
The competitive oxidation of a mixture of two alcohols by less than an equivalent amount of oxidant under the conditions developed by Swern (reaction of the alcohol at -60 deg C with Me2SCl+Cl- (4) generated from (COCl)2 and Me2SO in CH2Cl2 followed by re
