882883-10-5

Basic information

• Product Name: C₇H₆BO₄^(1-)
• CAS NO: 882883-10-5
• Molecular Weight: 164.933
• Mol File: 882883-10-5.mol

Chemical Properties

• CAS DataBase Reference: C₇H₆BO₄^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₇H₆BO₄^(1-)(882883-10-5)
• EPA Substance Registry System: C₇H₆BO₄^(1-)(882883-10-5)

Safety Data

• Hazardous Substances Data: 882883-10-5(Hazardous Substances Data)

Upstream product

• 850693-08-2 C₇H₄BF₃O₂^(2-) 

Relevant articles and documents

Substituent effects on aryltrifluoroborate solvolysis in water: Implications for Suzuki-Miyaura coupling and the design of stable 18F-labeled aryltrifluoroborates for use in PET imaging

(Chemical Equation Presented) Whereas electron withdrawing substituents retard the rate of aryltrifluoroborate solvolysis, electron-donating groups enhance it. Herein is presented a Hammett analysis of the solvolytic lability of aryltrifluoroborates where log(Ksolv) values correlate to a values with a ρ value of approximately -1. This work provides a predictable rubric for tuning the reactivity of boron for several uses including 18F-labeled PET reagents and has mechanistic implications for ArBF3-enhanced ligandless metal-mediated cross coupling reactions with aryltrifluoroborates.