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882884-04-0

[Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 882884-04-0 Structure

  • Basic information

    1. Product Name: [Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)]
    2. Synonyms: [Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)]
    3. CAS NO:882884-04-0
    4. Molecular Formula:
    5. Molecular Weight: 714.694
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 882884-04-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)](882884-04-0)
    11. EPA Substance Registry System: [Rh(triethylphosphine)3(9-phenyl-9-fluorenolato)](882884-04-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 882884-04-0(Hazardous Substances Data)

882884-04-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 882884-04-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,8,2,8,8 and 4 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 882884-04:
(8*8)+(7*8)+(6*2)+(5*8)+(4*8)+(3*4)+(2*0)+(1*4)=220
220 % 10 = 0
So 882884-04-0 is a valid CAS Registry Number.

882884-04-0Relevant articles and documents

Direct observation of β-aryl eliminations from Rh(I) alkoxides

Zhao, Pinjing,Incarvito, Christopher D.,Hartwig, John F.

, p. 3124 - 3125 (2006)

β-Aryl eliminations from a series of rhodium(I) alkoxides to form rhodium aryl complexes and free ketones are reported. Tertiary phenylmethoxide complexes [Rh(PEt3)n(OCPhRR′)] (n = 2, 3) were prepared via alcoholysis of {Rh(PEt3)2[N(SiMe3)2} by the corresponding alcohols HOCPhRR′ in the presence and absence of added PEt3. Heating of these complexes in the presence of added PEt3 generated the rhodium phenyl complex, (PEt3)3RhPh, and the corresponding ketones in good to high yields. Kinetic results are most consistent with irreversible β-phenyl elimination from a bisphosphine-ligated rhodium alkoxide complex. Such bisphosphine complexes result from ligand dissociation from the trisphosphine complexes and have been isolated in some cases. The bisphosphine complexes are stabilized by Rh-Cphenyl interactions, as evidenced by an X-ray structure, and this structure with a metal-aryl interaction likely illustrates the pathway for C-C bond cleavage. Copyright

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