88298-17-3

Upstream product

• 88298-13-9 (1R,2R)-2-((R)-1-Trimethylsilanyl-allyl)-1-vinyl-cyclohexanol 
• 71404-48-3 (R)-2-((R)-1-Trimethylsilanyl-allyl)-cyclohexanone 
• 1730-25-2 (E)-1-propenylmagnesium bromide 
• 3536-96-7 vinylmagnesium chloride 
• 822-87-7 2-Chlorocyclohexanone 

Relevant academic research and scientific papers

Construction of bicyclic ring systems via a transannular SmI 2-mediated ketone-olefin cyclization strategy

The development of novel methods and strategies for the formation of polycyclic ring structures is of utmost importance in organic synthesis. The present study describes the investigation of a transannular cyclization strategy for constructing bicyclic ri

HYDROXY GROUP-ASSISTED ISOMERIZATION AND ALKYLATION OF ALLYLSILANES IN BASIC MEDIA. α-(1-TRIMETHYLSILYLALLYL) KETONE AS AN α-ALKENYL KETONE EQUIVALENT

Regioselective protonation and alkylation of a certain hydroxyallylsilane have been effected in basic media.An application of these reactions to a facile preparation of 3-hydroxy-1,5-hexadiene systems has also been achieved.