883-21-6

Usage

Uses

Used in Chemical Synthesis:
1-Methoxy-2-naphthoic acid is used as a key intermediate in the synthesis of various organic compounds, including 2-(1-methoxy-2-naphthyl)-4,4-dimethyl-2-oxazoline. Its unique structure allows it to serve as a building block for the creation of complex molecules with specific properties and applications.
Used in the Synthesis of Specific Compounds:
1-Methoxy-2-naphthoic acid is utilized in the synthesis of several specific compounds, such as:
1. 1-sec-butyl-2-naphthoic acid
2. 1-tert-butyl-2-naphthoic acid
3. 1-ethyl-2-naphthoic acid
4. 1-vinyl-2-naphthoic acid
5. 1-phenyl-2-naphthoic acid
6. 1-(2,5-dimethylphenyl)-2-naphthoic acid
7. 2′-methoxy-[1,1′-binaphthalene]-2-carboxylic acid
These synthesized compounds may have various applications across different industries, such as pharmaceuticals, materials science, or as specialty chemicals, depending on their specific properties and characteristics.

InChI:InChI=1/C12H10O3/c1-15-11-9-5-3-2-4-8(9)6-7-10(11)12(13)14/h2-7H,1H3,(H,13,14)

Upstream product

• 50493-10-2 1-methoxy-2-naphthaldehyde 
• 390755-09-6 1-(1-methoxy-2-naphthoyloxy)-2-pyridone 

Downstream Products

• 53440-12-3 1,2,3,4-tetrahydro-2-naphthoic acid 
• 3299-82-9 1,4-dihydro-[2]naphthoic acid 
• 76635-76-2 2-(Hydroxymethyl)-1-methoxynaphthalene 
• 93-09-4 naphthalene-2-carboxylate 
• 70335-56-7 2-methyl-1,2,3,4-tetrahydronaphthalene-2-carboxylic acid 
• 31005-23-9 rac-(S)-2-methyl-1,2-dihydronaphthalene-2-carboxylic acid 
• 177606-84-7 1-Methoxy-naphthalene-2-carboxylic acid 2,6-di-tert-butyl-4-methoxy-phenyl ester 
• 51439-58-8 2-methoxy-1-naphthoic acid chloride 
• 786637-46-5 1-methoxy-naphthalene-2-carboxylic acid {4-[4-(2,3-dichloro-phenyl)-piperazin-1-yl]-butyl}-amide 
• 152565-78-1 3-(1'',3''-Dioxan-2''-yl)-1-(1'-methoxy-2'-naphthyl)propan-1-on 
• 52449-79-3 1-methoxy-[2]naphthonitrile 
• 1332452-84-2 1-(2-methylphenyl)-2-naphthoic acid 
• 85679-03-4 1-phenylnaphthalene-2-carboxylic acid 
• 1332452-83-1 1-(2-methoxyphenyl)-2-naphthoic acid 

Relevant academic research and scientific papers

Hydrogen peroxide oxidation of naphthalene derivatives catalyzed by poly (bis-1,2-diphenylene) diselenide

Oxidation of 1- and 2-substituted naphthalenes (1) with 30% hydrogen peroxide in the presence of poly(bis-1,2-diphenylene) diselenide (PPDS) has been investigated. Depending on the substrate used trans-2-carboxycinnamic acid (2), and its isomer, (1-oxo-1,3-dihydroisobenzofuran-1-yl)acetic acid (3) or 2-naphthoic acid (4b) was a major product. Oxidation of hydroxynaphthalenes 1b and 1c is a convenient way to obtain trans-2-carboxy cinnamic acid (2) in almost quantitative yield. The mechanism of the reaction is postulated.

Behavior of naphthoyloxyl and methoxynaphthoyloxyl radicals generated from the photocleavage of dinaphthoyl peroxides and 1-(naphthoyloxy)-2-pyridones

1-Naphthoyloxyl and 2-naphthoyloxyl radicals were generated from photocleavage of dinaphthoyl peroxides and 1-(naphthoyloxy)-2-pyridones in acetonitrile. The difference in product distribution between the precursors is ascribed to the contribution of the two-bond cleavage in the peroxide decomposition in the singlet state. A series of methoxynaphthoyloxyl radicals were also generated from the corresponding (methoxynaphthoyloxy)pyridones and their behavior was compared with that of unsubstituted naphthoyloxyl radicals. The introduction of a methoxy group in the naphthalene ring stabilizes the naphthoyloxyl radicals to prevent their decarboxylation completely and reduces remarkably their reactivities in the addition to olefins and hydrogen-atom abstraction. The structure of the naphthoyloxyl radicals was discussed on the basis of their absorption spectra and MO calculations.