88303-76-8Relevant academic research and scientific papers
Selective synthesis of glutaric acids from olefins
Depres,Greene
, p. 7065 - 7068 (1989)
Six representative glutaric acids have been regio- and stereoselectively prepared from the corresponding olefins in 49 to 65% overall yields. α,α-Dichlorocyclopentanones, readily available from the olefins by three-carbon annelation, are transformed via chloro enol acetates to the glutaric acids.
Titanium(IV) chloride-mediated ring cleavage and Michael addition of 3,3-dialkylcyclobutanones and 3-[(trimethylsilyl)methyl]-cyclobutanones
Okuno, Ryosuke,Matsuo, Jun-Ichi,Ishibashi, Hiroyuki
experimental part, p. 793 - 797 (2012/08/07)
β′-Chloro and β′,γ′-unsaturated trichlorotitanium enolates, which were formed in situ by titanium(IV) chloride-mediated ring cleavage of 3,3-dialkylcyclobutanones and 3-[(trimethylsilyl)methyl]cyclobutanones, reacted with enones to give Michael adducts wi
