88320-28-9Relevant academic research and scientific papers
Regiochemistry and Solvent Effect on the Reaction of 1-Selenoallyl Cations with N-Methylpyrrole
Renard, Michel,Hevesi, Laszlo
, p. 688 - 689 (2007/10/02)
Unsubstituted 1-methylseleno- and/or 1-phenylseleno-allyl cations undergo Friedel-Crafts reaction with N-methylpyrrole at their position 3 to give the adduct (4) while 1-seleno-3-dialkylallyl cations lead to (7) or (9) ia a highly solvent dependent manner, presumably via (5) which cannot be isolated.
GENERATION OF 1-SELENO-ALLYL CATIONS AND THEIR REACTIONS WITH FURAN AND PYRROLE
Renard, Michel,Hevesi, Laszlo
, p. 3911 - 3912 (2007/10/02)
1,3-bis(seleno)-propenes are valuable precursors of selenium stabilized allyl cations which react with furan and N-methyl pyrrole in a highly stereoselective fashion to give electrophilic substitution products.
