88326-24-3

Basic information

• Product Name: ethyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(II)
• CAS NO: 88326-24-3
• Molecular Weight: 595.204
• Mol File: 88326-24-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(II)(CAS DataBase Reference)
• NIST Chemistry Reference: ethyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(II)(88326-24-3)
• EPA Substance Registry System: ethyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(II)(88326-24-3)

Safety Data

• Hazardous Substances Data: 88326-24-3(Hazardous Substances Data)

Upstream product

• 896-33-3 ethyltriphenylphosphonium chloride 
• 121714-78-1 iron(III) chloride hexahydrate 
• 88326-20-9 bis(ethyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II) 

Relevant articles and documents

Kinetics of the Chemical and Electrochemical, Reversible Oxidation of Bis(dithiooxalato-S,S')cuprate(II), 2-. A Facile, Light-Activated, Intramolecular Electron Transfer and Cleavage of the C-C Bond in the Coordinated Dto Ligands in the - Anion

The rates of reaction of bis(dithiooxalato-S,S')cuprate(II), 2-, with Cu(II) and Fe(III) have been measured and the corresponding rate constants and activation parameters are reported.In addition, the electrochemistry of this complex and of the oxidation product - was studied in detail.The - anion undergoes a light-activated, intramolecular, Dto -> Cu two-electron transfer with cleavage of the C-C bond in the Dto ligand and generation of gaseous SCO.Addition of triphenylphosphine to - in the presence or absence of light also results in intramolecular redox and cleavage of the C-C bond.