88343-92-4

Basic information

• Product Name: Benzenemethanol, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-a-(4-nitrophenyl)-
• CAS NO: 88343-92-4
• Molecular Formula: C21H27NO4
• Molecular Weight: 357.45
• Mol File: 88343-92-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-a-(4-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-a-(4-nitrophenyl)-(88343-92-4)
• EPA Substance Registry System: Benzenemethanol, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-a-(4-nitrophenyl)-(88343-92-4)

Safety Data

• Hazardous Substances Data: 88343-92-4(Hazardous Substances Data)

Upstream product

• 128-39-2 2,6-di-tert-butylphenol 
• 555-16-8 4-nitrobenzaldehdye 
• 718-36-5 (p-nitrobenzylidene)(tert-butyl)amine 
• 26378-36-9 2-tert-butyl-3-(4-nitrophenyl)-1,2-oxaziridine 
• 576-26-1 2.6-dimethylphenol 

Downstream Products

• 183666-73-1 2,6-di-tert-butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-diene-1-one 

Relevant articles and documents

Copper-Catalyzed 1,6-Hydrodifluoroacetylation of para-Quinone Methides at Ambient Temperature with Bis(pinacolato)diboron as Reductant

An original and efficient copper-catalyzed 1,6-hydrodifluoroacetylation of para-quinone methides with difluoroalkyl bromides has been described with bis(pinacolato)diboron (B2pin2) as reductant. In this reaction, a new C(sp3)–CF2bond is constructed under smart conditions. A broad substrate scope of para-quinone methides (p-QMs) make this protocol very practical and attractive. Preliminary mechanistic studies manifested that a difluoroalkyl radical pathway was involved in this reaction. Also the presence of the diboron reagent was an essential requisite in this transformation. (Figure presented.).