88354-75-0Relevant academic research and scientific papers
159. On the Stereochemistry of Allylmetal-Aldehyde Condensations
Denmark, Scott E.,Weber, Eric J.
, p. 1655 - 1660 (2007/10/02)
The stereochemical course of the intramolecular allylsilane-aldehyde condensation of 1a has been investigated.A modest preference for the product arising from a synclinal orientation of double bonds was observed with Lewis-acid catalysts.Cyclization induced by fluoride ion resulted in stereochemical reversal.
