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88362-52-1

(S)-(-)-(Z)-3-(2-butenyl)-4,5-dihydro-2-methyl-4-(1-methylethyl)oxazolium 4-methylbenzenesulfonate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 88362-52-1 Structure

  • Basic information

    1. Product Name: (S)-(-)-(Z)-3-(2-butenyl)-4,5-dihydro-2-methyl-4-(1-methylethyl)oxazolium 4-methylbenzenesulfonate
    2. Synonyms:
    3. CAS NO:88362-52-1
    4. Molecular Formula:
    5. Molecular Weight: 353.483
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 88362-52-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (S)-(-)-(Z)-3-(2-butenyl)-4,5-dihydro-2-methyl-4-(1-methylethyl)oxazolium 4-methylbenzenesulfonate(CAS DataBase Reference)
    10. NIST Chemistry Reference: (S)-(-)-(Z)-3-(2-butenyl)-4,5-dihydro-2-methyl-4-(1-methylethyl)oxazolium 4-methylbenzenesulfonate(88362-52-1)
    11. EPA Substance Registry System: (S)-(-)-(Z)-3-(2-butenyl)-4,5-dihydro-2-methyl-4-(1-methylethyl)oxazolium 4-methylbenzenesulfonate(88362-52-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 88362-52-1(Hazardous Substances Data)

88362-52-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 88362-52-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,3,6 and 2 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 88362-52:
(7*8)+(6*8)+(5*3)+(4*6)+(3*2)+(2*5)+(1*2)=161
161 % 10 = 1
So 88362-52-1 is a valid CAS Registry Number.

88362-52-1Downstream Products

88362-52-1Relevant articles and documents

AUXILIARY-REAGENT MEDIATED ASYMMETRIC INDUCTION IN THE AZA-CLAISEN REARRANGEMENT

Kurth, Mark J.,Decker, Owen H. W.

, p. 4535 - 4538 (1983)

Chiral induction (72-74percent diastereomeric excess) in an auxiliary-reagent mediated aza-Claisen rearrangement yielding 2- and 3-methylpent-4-enoic acids has been demonstrated.

Enantioselective Preparation of 3-Substituted-4-pentenoic Acids via the Claisen Rearrangement

Kurth, Mark J.,Decker, Owen H. W.

, p. 5769 - 5775 (2007/10/02)

Asymmetric C-C bond formation via the diastereoselective aza-Claisen rearrangement of N-allylketene N,O-acetal 4 is described.The starting materials, allylic alkylating agant 1 and optically pure oxazoline 2, are easily prepared and, in a one-pot procedure, generate rearranged oxazolines 5 in 52-94percent diastereomeric excess.The overall chemical yields for 2 -> 5 range from 51 to 78percent.The aza-Claisen rearrangement (4 -> 5) proceeds with excellent N,O-acetal face selectivity and with good to excellent chair selectivity.Hydrolysis of rearranged oxazoline 5 completes an enantioselective synthesis of 3-substituted pent-4-enoic acids.

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