883746-44-9

Upstream product

• 1189-71-5 isocyanate de chlorosulfonyle 
• 2216-51-5 (-)-menthol 

Downstream Products

• 883746-25-6 N,N-diethyl-N-{[({[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]-oxy}carbonyl)amino]sulfonyl}ethanaminium inner salt 
• 883746-36-9 (1R,2R)-benzoic acid 2-(1R,2S,5R)-(2-isopropyl-5-methylcyclohexyloxycarbonylamino)cyclohex-3-enyl ester 
• 883746-38-1 (1S,2S)-benzoic acid 2-(1R,2S,5R)-(2-isopropyl-5-methylcyclohexyloxycarbonylamino)cyclohex-3-enyl ester 
• 883746-27-8 (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl [(1R,2R)-2-(benzoyloxy)cyclohexyl]carbamate 
• 1010104-72-9 2,2-Dioxo-3a,6,7,7a-tetrahydro-2λ⁶-benzo[1,2,3]oxathiazole-3-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant academic research and scientific papers

New options for the reactivity of the burgess reagent with epoxides in both racemic and chiral auxiliary modes - Structural and mechanistic revisions, computational studies, and application to synthesis

The reaction of the chiral auxiliary version of the Burgess reagent with epoxides yields diastereomeric pairs of sulfamldates, which, lead, to cis and trans amino alcohols in each, enantiomeric series. Experimental and spectral, details are provided for a

Chiral version of the Burgess reagent and its reactions with epoxides

A chiral auxiliary version of the Burgess reagent was prepared, and its reactions with epoxides were studied. Diastereomeric sulfamidates were converted to both enantiomers of protected trans-amino alcohols with ee of 84-98%. Georg Thieme Verlag Stuttgart