88393-72-0Relevant academic research and scientific papers
Tungsten-, molybdenum-, and cerium-promoted regioselective and stereospecific halogenation of 2,3-epoxy alcohols and 2,3-epoxy sulfonamides
Wang, Chuan,Yamamoto, Hisashi
, p. 5937 - 5939 (2014)
The first catalytic regioselective and stereospecific halogenation of 2,3-epoxy alcohols and 2,3-epoxy sulfonamides has been developed. Under the catalysis of commercially available W- or Mo-salts, complemented by the method using cerium halides, the C-3
Regio and Diastereoselective Oxygen assisted Opening by Monochloroborane-Dimethylsulfide of Epoxides to anti Chlorohydrins.
Bovicelli, Paolo,Lupattelli, Paolo,Bersani, Maria Teresa,Mincione, Enrico
, p. 6181 - 6182 (2007/10/02)
The opening reaction of epoxides by monochloroborane-dimethylsulfide 1 proceeds by oxygen anchimeric assistance in a regio and diastereoselective manner to give the corresponding anti chlorohydrins.
