88412-18-4

Upstream product

• 108-24-7 acetic anhydride 
• 89731-36-2 (1aR,3aS,5R,6S,7R,7aS,7bS)-6-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxymethyl)-hexahydro-1,3,4-trioxa-cyclopropa[a]naphthalen-7-ol 
• 88392-80-7 (2R,3S,4R,4aR,8aS)-3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4,4a,8a-tetrahydro-2H,7H-pyrano[2,3-b]pyran-4-ol 
• 89731-36-2 (1aS,3aS,5R,6S,7R,7aS,7bR)-6-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxymethyl)-hexahydro-1,3,4-trioxa-cyclopropa[a]naphthalen-7-ol 
• 88412-17-3 Acetic acid (2R,3S,4R,4aR,8aS)-3-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4,4a,8a-tetrahydro-2H,7H-pyrano[2,3-b]pyran-4-yl ester 
• 89731-34-0 1,6-anhydro-4-O-benzyl-2-deoxy-2-C-(3-hydroxypropynyl)-β-D-glucopyranose 
• 33208-47-8 4-O-benzyl-1,6:2,3-dianhydro-β-D-mannopyranose 
• 110115-27-0 (1R,2S,3R,4R,5R)-2-Benzyloxy-4-((Z)-3-hydroxy-propenyl)-6,8-dioxa-bicyclo[3.2.1]octan-3-ol 
• 110046-81-6 1,6-anhydro-4-O-benzyl-2-deoxy-2-C-(3-tert-butyldimethylsilyloxyprop-1-ynyl)-β-D-glucopyranose 

Downstream Products

• 88392-84-1 (2S,3S,4R,4aR,5S,6S,8aS)-4,5-Bis-benzyloxy-3-hydroxy-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-carbaldehyde 
• 88392-83-0 (2R,3S,4R,4aR,5S,6S,8aS)-4,5-Bis-benzyloxy-2-hydroxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-3-ol 
• 88392-86-3 (3S,4S,4aR,6R,8aR,9aS,10R,10aS)-4,10-Bis-benzyloxy-6-methoxy-3-methyl-3,4,4a,6,8a,9a,10,10a-octahydro-2H-1,5,9-trioxa-anthracene 
• 88392-87-4 (2R,3aS,4R,4aR,5S,6S,8aS,9aR)-4,5-Bis-benzyloxy-2-methoxy-6-methyl-decahydro-1,3,8,9-tetraoxa-cyclopropa[a]anthracene 
• 88392-85-2 (2R,3S,4R,4aR,5S,6S,8aS)-4,5-Bis-benzyloxy-2-((E)-2-[1,3]dioxolan-2-yl-vinyl)-6-methyl-hexahydro-pyrano[2,3-b]pyran-3-ol 
• 88392-88-5 (3S,4S,4aR,6R,7R,8S,8aR,9aS,10R,10aS)-4,10-Bis-benzyloxy-6,7-dimethoxy-3,8-dimethyl-decahydro-1,5,9-trioxa-anthracene 
• 88424-60-6 Acetic acid (2R,3S,4R,4aR,5S,6S,8aS)-3-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-hydroxy-6-methyl-hexahydro-pyrano[2,3-b]pyran-4-yl ester 
• 88392-81-8 Acetic acid (2R,3S,4R,4aR,5R,6S,8aS)-3-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-hydroxy-6-methyl-hexahydro-pyrano[2,3-b]pyran-4-yl ester 

Relevant academic research and scientific papers

New Strategy for Carbohydrate-Based Syntheses of Multichiral Arrays: Pyranosidic Homologation. 3.

A process of pyranosidic homologation has been developed whereby "satellite" pyranosides are attached to the front and rear of a "backbone" pyranoside.The resulting manifold has capacity for eight contiguous chiral centers, two of which surive from the st

PYRANOSIDIC HOMOLOGATION: PART II: EXTENDING THE CARBOHYDRATE TEMPLATE VIA VICINAL (SECONDARY) HYDROXYLS

The oxyrane ring of the dianhydro sugar (3b) is opened regioselectively by the dianion (4b), and reaction of the derived allylic alcohol (7b) with trifluoroacetic acid gives the oxa-cis-decalin (8b), which can be epoxidised selectively from the endo or ex