88419-71-0Relevant academic research and scientific papers
A NEW ONE-POT METHOD FOR α,α-DIALLYLATION OF KETONES BASED ON THE PALLADIUM-CATALYZED REACTION OF ALLYLIC CARBONATES AND ALLYL β-KETO CARBOXYLATES UNDER NEUTRAL CONDITIONS
Shimizu, Isao,Ohashi, Yukihiro,Tsuji, Jiro
, p. 3865 - 3868 (2007/10/02)
A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed.Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.
