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• 86292-20-8 Fe⁽²⁺⁾*SC₆H₄SCH₂CH₂SCH₂CH₂SC₆H₄S^(2-)*P(OC₆H₅)3=[Fe(SC₆H₄SCH₂CH₂SCH₂CH₂SC₆H₄S)(P(OC₆H₅)3)] 
• 60-34-4 methylhydrazine 

Relevant academic research and scientific papers

UEBERGANGSMETALLKOMPLEXE MIT SCHWEFELLIGANDEN. VI. SYNTHESE DER FUENF- UND SECHSZAEHNIGEN THIOETHERTHIOL-LIGANDEN dpttd-H2 = 2,3,11,12-DIBENZO-1,4,7,10,13-PENTATHIATRIDECAN BZW. dhthd-H2 = 2,3,14,15-DIBENZO-1,4,7,10,13,16-HEXATHIAHEXADECAN SOWIE IHRER FeII- Mo0- UND MoII-CARBONYL..

Hydrolysis of by HCl in THF yields the pentadentate thioetherthiol ligand dpttd-H2 = 2,3,11,12-dibenzo-1,4,7,10,13-pentathiatridecane in the free state.The same principle of synthesis leads also to the hexadentate ligand dhthd-H2 = 2,3,14,15-dibenzo-1,4,7,10,13,16-hexathiahexadecane; 2- is alkylated by BrC2H4SC2H4SC2H4Br to , which is subsequently hydrolyzed.The reaction of dpttd2- salts with Mo(CO)6 yields 2-, where the dpttd ligand functions as tridentate ligand; or yield with pentadentate dpttd.This complex with PMe3 yields .The reaction of the potentially hexadentate dhthd-H2 with MoII-carbonyl complexes yields a mixture of and .Furthermore, , which contains totally chlorinated benzene rings as well as the methylhydrazine complex , were obtained as new derivatives of .