884492-76-6Relevant academic research and scientific papers
Four new cadmium(II) homophthalate diimine complexes: Syntheses, structures and fluorescence
He, Jin-Run,Wang, Yu-Ling,Bi, Wen-Hua,Wang, Yan-Qin,Cao, Rong
, p. 1239 - 1246 (2006)
Four new complexes of homophthalate (hpht), [Cd(hpht)(phen)]n (1), [Cd(hpht)(2,2′-bpy)]n (2), [Cd(hpht)(2,2′-bpy) (H2O)]n ? 2nH2O (3), [Cd(hpht)(4,4′- bpy)]n ? nH2O (4), have been solvothermally synthesized and characterized. Both 1 and 2 are 1-D double-chains which are further extended to 2-D layer structure by the π-π interaction of phen (for 1) and 2,2′-bpy (for 2). Complex 3 is linear chain which is stacked to 3-D supramolecular network though the π-π interaction and hydrogen bonding. Complex 4 features a 2-D network formed by the linkages of bench-like chains though 4,4′-bpy. Both 1 and 2 exhibit intense blue fluorescence emission and 3 produces a green fluorescence, while 4 features a unique and very strong red fluorescence. Complexes 1-4 may be potential candidates for photoactive materials.
