88489-51-4Relevant academic research and scientific papers
Electronic absorption spectra of diorganogermylenes in matrices: Formation of diorganogermylene complexes with heteroatom-containing substrates
Ando, Wataru,Itoh, Hiroyuki,Tsumuraya, Takeshi
, p. 2759 - 2766 (2008/10/08)
Diorganogermylenes were generated in hydrocarbon matrices at 77 K by the photolysis of 7-germanorbornadienes 1a-e or bis(trimethylsilyl)germanes 2a-g. The germylenes show electronic absorption bands at 420-558 nm. The germylenes react with heteroatom-containing substrates (R2O, R2S, R3P, R3N, RCl, and ROH) to form adducts, which show characteristic absorption bands at shorter wavelengths than those of germylenes.
