885065-68-9

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 164145-68-0 (R)-1-((R)-1,4-dioxaspiro[4.5]decan-2-yl)but-3-en-1-ol 
• 885065-70-3 Toluene-4-sulfonic acid (2S,4R)-4-(tert-butyl-diphenyl-silanyloxy)-4-(R)-1,4-dioxa-spiro[4.5]dec-2-yl-2-hydroxy-butyl ester 
• 885065-66-7 (4R,6R,7R)-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxyoctan-4-yl 5'-hexenoate 
• 885065-67-8 (2R,3R,5R)-3-tert-butyldiphenylsilyloxy-5-(5'-hexenoyloxy)octane-1,2-diol 
• 885065-65-6 (4R,6R,7R)-6-tert-butyldiphenylsilyloxy-7,8-cyclohexylidenedioxyoctan-4-ol 
• 885065-63-4 (2S,4R,5R)-4-tert-butyldiphenylsilyloxy-5,6-cyclohexylidenedioxyhexane-1,2-diol 
• 885065-64-5 (2S,4R,5R)-4-tert-butyldiphenylsilyloxy-5,6-cyclohexylidenedioxy-1,2-epoxyhexane 
• 885065-62-3 (4R,5R)-4-tert-butyldiphenylsilyloxy-5,6-cyclohexylidenedioxyhex-1-ene 
• 885065-71-4 Hex-5-enoic acid (1R,3R,4R)-3-(tert-butyl-diphenyl-silanyloxy)-4,5-bis-methanesulfonyloxy-1-propyl-pentyl ester 

Relevant academic research and scientific papers

An asymmetric synthesis of 7-hydroxy-9-propylnonenolide (herbarumin III)

An asymmetric synthesis of herbarumin III has been developed using (R)-cyclohexylidene glyceraldehyde 1 as the chiral template. The key steps of the synthesis were the enantioselective preparation of the required homoallylic alcohol from 1, an asymmetric