88521-97-5Relevant articles and documents
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions
Gil-Negrete, José M.,Pérez Sestelo, José,Sarandeses, Luis A.
supporting information, p. 1453 - 1456 (2018/02/19)
Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can
Microwave-assisted copper-catalyzed cross-coupling reaction of alkynes with aryl iodides and vinyl halides
Tsai, Wen-Ting,Lin, Yun-Yung,Wang, Yu-Jen,Lee, Chin-Fa
supporting information; experimental part, p. 1507 - 1510 (2012/06/18)
The microwave-assisted, copper-catalyzed coupling of terminal alkynes with aryl iodides and vinyl halides is reported. In general, the reactions are completed in 10-30 min using 2-5 mol% [CuI(xantphos)] as a catalyst to provide the corresponding alkynes and enynes in good to excellent yields. A broad spectrum of aryl iodides, vinyl iodides, and bromides are coupled with aryl- and alkyl alkynes.
Copper-catalyzed cross-coupling of 1-iodoalkynes with organostannanes
Kang, Suk-Ku,Kim, Won-Yeob,Jiao, Xianghua
, p. 1252 - 1254 (2007/10/03)
Copper-catalyzed cross-coupling of 1-iodoalkynes with organostannanes was readily achieved in the presence of CuI (10 mol%) in DMF at room temperature for 6 hours by adding 1-iodoalkynes slowly to organostannanes.
