885516-55-2Relevant articles and documents
Quasi-thermoneutral P → B interactions within di- and tri-phosphine boranes
Bontemps, Sebastien,Bouhadir, Ghenwa,Dyer, Philip W.,Miqueu, Karinne,Bourissou, Didier
, p. 5149 - 5151 (2008/10/09)
Spectroscopic, structural, and theoretical evidence is provided for both open (no intramolecular P → B interaction) and closed (with intramolecular P → B interaction) forms of the di- and tri-phosphine boranes [o-(iPr 2P)C6H4/s
Rhodium(I) complexes of a PBP ambiphilic ligand: Evidence for a metal→borane interaction
Bontemps, Sebastien,Gornitzka, Heinz,Bouhadir, Ghenwa,Miqueu, Karinne,Bourissou, Didier
, p. 1611 - 1614 (2008/02/01)
To and fro: Diphosphanylborane derivative 1 behaves as a tridentate, ambiphilic ligand towards rhodium(I) fragments (see picture). The presence of metal-→borane interactions in the resulting square-pyramidal complexes is highlighted by structural analyses