88567-32-2Relevant academic research and scientific papers
Synthetic Studies on a Picrotoxane Sesquiterpene, Coriamyrtin. II. An Effective Stereocontrolled Synthesis of the Picrotoxane Skeleton Except for a C1 Unit at the C9 Position and Functionalization of the Five-membered Ring
Tanaka, Kiyoshi,Uchiyama, Fumiaki,Ikeda, Takaharu,Inubushi, Yasuo
, p. 1958 - 1971 (2007/10/02)
The picrotoxane skeleton (5) except for a C1 unit at the C9 position was effectively synthesized starting from protoanemonin and 2-methyl-1,3-cyclopentanedione through five steps.The key reaction of this synthesis was the Grignard re
