88596-66-1Relevant academic research and scientific papers
APPROACHES TOWARDS THE SYNTHESIS OF ALLENYL AZIDES
L'abbe, Gerrit,Mahy, Michel,Bollyn, Marcus,Germain, Gabriel,Scheefer, Guy
, p. 881 - 892 (2007/10/02)
Methods which are known to produce allenes under mild conditions have failed to synthesize the yet unknown title compounds.These are (i) azide substitution of propargyl sulfonates, (ii) reactions of α-azido acid chlorides with ynamines, and (iii) Wittig condensation of α-azido acid chlorides with phosphorus ylides.The reaction products obtained are respectively azidoalkyl-1,2,3-triazoles (4), pyrrolinones (6) or pyridines (8), and a disubstituted ylide (11) or the fused triazole 12.
