886579-04-0

Basic information

• Product Name: Bz₂SnCl(2-amino-1-cyclopentene-1-carbodithioic acid^(1-))
• CAS NO: 886579-04-0
• Molecular Weight: 494.696
• Mol File: 886579-04-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bz₂SnCl(2-amino-1-cyclopentene-1-carbodithioic acid^(1-))(CAS DataBase Reference)
• NIST Chemistry Reference: Bz₂SnCl(2-amino-1-cyclopentene-1-carbodithioic acid^(1-))(886579-04-0)
• EPA Substance Registry System: Bz₂SnCl(2-amino-1-cyclopentene-1-carbodithioic acid^(1-))(886579-04-0)

Safety Data

• Hazardous Substances Data: 886579-04-0(Hazardous Substances Data)

Upstream product

• 20735-33-5 2-aminocyclopent-1-ene-1-carbodithioic acid 
• 3002-01-5 dibenzyltin(IV) dichloride 

Relevant articles and documents

Synthesis and crystal structures of new complexes of di- and tribenzyltin 2-amino-1-cyclopentene-1-carbodithioates

Treatment of dibenzyltin dichloride with 1 equiv. of 2-amino-1- cyclopentene-1-carbodithioic acid (ACDA) gave Bz2SnCl(ACDA) (1) that contains five coordinate tin. Reaction of 2 equiv. of ammonium 2-amino-1-cyclopentene-1-carbodithioic acid (AACD) with Bz2SnCl 2 and then recrystallization from THF produced Bz2Sn(ACDA) 2 ? THF 2 in which the coordination geometry around the Sn is highly distorted from octahedral. Bz3Sn(ACDA) (3) was obtained from reaction of Bz3SnCl with 1 equiv. of AACD. The crystal structure of 3 indicates a Sn-S′ interaction [3.0823(5) ?] that distorts the tin coordination geometry from that of an ideal tetrahedron. In 1-3 the tin atom is also coordinated to one carbon atom of each benzyl group. The products were characterized by IR and NMR (1H, 13C, 119Sn) spectroscopy and elemental analysis.