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pentacarbonyl Complexes of Chromium and Tungsten
Fischer, Helmut,Zeuner, Siegfried
, p. 1365 - 1368 (2007/10/02)
pentacarbonyl complexes of chromium and tungsten, (CO)5M (M = Cr, R = H and M = W, R = NMe2, OMe, Me, H, Br, CF3) react with phenylisoselenocyanate or potassium selenocyanate inserting selenium into the metal-carbene bond to give the first η1-bonded bisarylselenoketone(carbonyl) complexes, (CO)5M.The compounds were characterized by analytical and spectroscopic means. - Keywords: Selenoketone Complexes, Insertion Reaction
