88686-01-5

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 88686-09-3 1-((2E,4E)-6-Ethyl-7-methyl-nona-2,4,8-triene-1-sulfonyl)-4-methyl-benzene 
• 88686-03-7 (2E,7E,9E)-6-Ethyl-5-methyl-11-(toluene-4-sulfonyl)-undeca-2,7,9-trienoic acid ethyl ester 
• 88686-05-9 (2E,4E)-6-Ethyl-7-methyl-nona-2,4,8-trien-1-ol 

Downstream Products

• 88686-10-6 [(1R,2R,3aR,4R,5S,7aR)-1-Ethyl-2-methyl-5-(toluene-4-sulfonylmethyl)-2,3,3a,4,5,7a-hexahydro-1H-inden-4-yl]-acetic acid methyl ester 
• 88685-99-8 (3R,3aS,5aR,6R,7R,8aR,8bR)-6-Ethyl-7-methyl-3-(toluene-4-sulfonyl)-3,3a,5a,6,7,8,8a,8b-octahydro-1H-as-indacen-2-one 
• 88685-98-7 (3aR,5aS,6S,7S,8aS,8bR)-6-Ethyl-7-methyl-3,3a,5a,6,7,8,8a,8b-octahydro-1H-as-indacen-2-one 

Relevant academic research and scientific papers

Ikarugamycin : Total Synthesis of the Decahydro-as-indacene Portion

An efficient , stereoselective synthesis of octahydro-as-indacenone 2 , the carbocycle fragment of the antibiotic ikarugamycin , is described.The prominent step in the sequence is an intramolecular Diels-Alder reaction, which establishes the relative stereochemistry of 2.