88691-43-4

Basic information

• Product Name: Silane, trimethyl[2-(3-nitrophenyl)ethenyl]-, (E)-
• CAS NO: 88691-43-4
• Molecular Formula: C11H15NO2Si
• Molecular Weight: 221.331
• Mol File: 88691-43-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[2-(3-nitrophenyl)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[2-(3-nitrophenyl)ethenyl]-, (E)-(88691-43-4)
• EPA Substance Registry System: Silane, trimethyl[2-(3-nitrophenyl)ethenyl]-, (E)-(88691-43-4)

Safety Data

• Hazardous Substances Data: 88691-43-4(Hazardous Substances Data)

Upstream product

• 645-00-1 m-iodonitrobenzene 
• 754-05-2 ethenyltrimethylsilane 
• 58032-84-1 (3-nitrophenyl)methanesulfonyl chloride 
• 18107-18-1 diazomethyl-trimethyl-silane 

Relevant articles and documents

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

The direct olefination of aryl/alkyl halides with trimethylsilyldiazomethane (TMSD) as a C1- or C2-unit was achieved successfully via a metal carbene migratory insertion process, which offered a new access to afford (E)-vinyl silanes and (E)-silyl-substituted α,β-unsaturated amides in good yields and high chemoselectivity.

PALLADIUM-CATALYSED ARYLATION OF VINYLTRIMETHYLSILANE IN THE PRESENCE OF SILVER NITRATE

A series of arylated vinyltrimethylsilanes have been prepared by means of Heck Arylation in the presence of silver nitrate, which serves to suppress the elimination of the silicon group and enhance the reaction rate.