887266-68-4Relevant articles and documents
Enantioselective synthesis of axially chiral anilides through rhodium-catalyzed [2+2+2] cycloaddition of 1,6-diynes with trimethylsilylynamides
Tanaka, Ken,Takeishi, Kenzo,Noguchi, Keiichi
, p. 4586 - 4587 (2006)
We have developed a rhodium-catalyzed enantioselective intermolecular [2+2+2] cycloaddition of 1,6-diynes with trimethylsilylynamides for the synthesis of axially chiral anilides. The axial chirality is constructed at the formation of benzene rings with h
Preparation of enantioenriched axially chiral anilides via [2+2+2] cycloaddition of 1,6-diynes with trimethylsilylynamides
Tanaka, Ken,Takeishi, Kenzo
, p. 2920 - 2923 (2008/03/13)
The rhodium-catalyzed enantioselective [2+2+2] cycloaddition of 1,6-diynes with teimethylsilylynamides provides enantioenriched axially chiral anilides in poor to good yields with good to excellent enantioselectivity. Trimethylsilylynamides can be readily