88738-21-0Relevant articles and documents
2-(2-pyridyl)ethylsilyl group as a new class of electroauxiliary. Fine tuning of the electron transfer driven reactions by the dynamic coordination to silicon
Yoshida, Jun-Ichi,Suga, Seiji,Fuke, Ken-Ichi,Watanabe, Mitsuru
, p. 251 - 252 (1999)
The introduction of 2-(2-pyridyl)ethyl group on silicon decreases the oxidation potentials of silyl-substituted heteroatom compounds. The molecular orbital calculations indicate that this effect is attributed to the dynamic coordination of the pyridyl gro
lithium and lithium. Convenient Reagents for the Facile Conversion of Aldehydes, Ketones, and 3-Alkoxy Enones into Ketene O,S-Acetal Derivatives
Hackett, Steven,Livinghouse, Tom
, p. 879 - 885 (2007/10/02)
The title organometalics have been found to react in the 1,2-sense with a variety of carbonyl compounds to provide O,S-acetal and ketene O,S-acetal derivatives in high yield.The β,γ-unsaturated O,S-acetals obtained via the reaction of methoxy(phenylthio)
