88754-01-2

Upstream product

• 108-24-7 acetic anhydride 
• 91621-58-8 trans-(R,R)(S,S)-4-phenyl-1-<1-hydroxy-2-(dimethylphenylsilyl)propyl>cyclohexanol 
• 91621-58-8 trans-(S,R)(R,S)-4-phenyl-1-<1-hydroxy-2-(dimethylphenylsilyl)propyl>cyclohexanol 
• 91621-58-8 cis-(S,R)(R,S)-4-phenyl-1-<1-hydroxy-2-(dimethylphenylsilyl)propyl>cyclohexanol 
• 75583-57-2 lithium bis(dimethyl(phenyl)silyl)cuprate 
• 88823-75-0 trans-(Z)-4-phenyl-1-(1-propenyl)cyclohexyl acetate 
• 88823-74-9 cis-(E)-4-phenyl-1-(1-propenyl)cyclohexyl acetate 
• 88754-00-1 (S,R/R,S)-dimethylphenyl-<1-methyl-2-(4-phenylcyclohexylidenyl)ethyl>silane 
• 88753-99-5 trans-(E)-4-phenyl-1-(1-propenyl)cyclohexyl acetate 
• 88823-73-8 cis-(Z)-4-phenyl-1-(1-propenyl)cyclohexyl acetate 
• 88754-00-1 (S,S/R,R)-dimethylphenyl-<1-methyl-2-(4-phenylcyclohexylidenyl)ethyl>silane 

Downstream Products

• 88823-80-7 trans-(Z)-4-phenyl-1-(1-propenyl)cyclohexanol 
• 88823-79-4 cis-(E)-4-phenyl-1-(1-propenyl)cyclohexanol 

Relevant academic research and scientific papers

STEREOSPECIFIC SYNTHESES AND REACTIONS OF ALLYL- AND ALLENYL-SILANES

The stereospecifically anti synthesis of allyl- and allenyl-silanes by the reaction of a silylcuprate reagent with allyl and propargyl acetates is described.The SE2' reactions of these silanes with various electrophiles are shown to proceed wit

STEREOSPECIFICITY IN THE SYNTHESIS OF ALLYLSILANES FROM TERTIARY ALLYLIC ACETATES

The tertiary allylic acetates (1-4) and the propargylic acetates (14 and 15) react with our silyl-cuprate reagent (5) to give, in a cleanly anti manner, the stereodefined allylsilanes (6 and 7) and allenylsilanes (16 and 17).