88754-14-7Relevant academic research and scientific papers
STEREOSPECIFIC SYNTHESES AND REACTIONS OF ALLYL- AND ALLENYL-SILANES
Fleming, Ian,Terrett, Nicholas K.
, p. 99 - 118 (2007/10/02)
The stereospecifically anti synthesis of allyl- and allenyl-silanes by the reaction of a silylcuprate reagent with allyl and propargyl acetates is described.The SE2' reactions of these silanes with various electrophiles are shown to proceed wit
THE STEREOCHEMISTRY OF SOME SE2' REACTIONS OF ALLYL- AND ALLENYLSILANES
Fleming, Ian,Terrett, Nicholas K.
, p. 4153 - 4156 (2007/10/02)
The SE2' reactions of 1 and 2 with a range of electrophiles are predominantly anti in the allylsilane portion of the molecule, but this offset, to a greater or lesser extent, by axial or equatorial preferences in the ring system.
