887612-20-6Relevant articles and documents
Enantioselective total synthesis of bistramide A
Crimmins, Michael T.,DeBaillie, Amy C.
, p. 4936 - 4937 (2007/10/03)
The enantioselective synthesis of bistramide A has been achieved with a longest linear sequence of 18 steps. The synthetic strategy involves the use of a distereoselective glycolate alkylation, an aldol addition of a chlorotitanium enolate of N-acylthiazolidinthione, and a Sharpless asymmetric epoxidation to synthesize the three key fragments. Copyright