887616-38-8

Basic information

• Product Name: 3-Penten-2-one, 4-[4-(1,1-dimethylethyl)phenyl]-5,5,5-trifluoro-, (3E)-
• CAS NO: 887616-38-8
• Molecular Formula: C15H17F3O
• Molecular Weight: 270.295
• Mol File: 887616-38-8.mol

Chemical Properties

• CAS DataBase Reference: 3-Penten-2-one, 4-[4-(1,1-dimethylethyl)phenyl]-5,5,5-trifluoro-, (3E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Penten-2-one, 4-[4-(1,1-dimethylethyl)phenyl]-5,5,5-trifluoro-, (3E)-(887616-38-8)
• EPA Substance Registry System: 3-Penten-2-one, 4-[4-(1,1-dimethylethyl)phenyl]-5,5,5-trifluoro-, (3E)-(887616-38-8)

Safety Data

• Hazardous Substances Data: 887616-38-8(Hazardous Substances Data)

Upstream product

• 63488-10-8 4-tert-butylmagnesium bromide 

Downstream Products

• 887616-50-4 (E)-4-(4-t-butylphenyl)-5,5,5-trifluoro-3-penten-2-yl mesylate 
• 887616-44-6 (E)-4-(4-t-butylphenyl)-5,5,5-trifluoro-3-penten-2-ol 

Relevant articles and documents

Palladium-catalyzed regio- and stereoselective formate reduction of fluorine-containing allylic mesylates. A new entry for the construction of a tertiary carbon attached with a fluoroalkyl group

The regioselective palladium-catalyzed formate reduction of γ-fluoroalkylated allylic esters is described. Reduction of the allylic esters under the influence of palladium with a monodentate phosphine ligand proceeded preferentially at the γ position, the corresponding reduction products with a fluoroalkyl group at the tertiary carbon being afforded in high yields. When the chiral allylic ester was employed, complete chirality transfer was observed, leading to the optically active materials in high yields.