887777-00-6Relevant articles and documents
Preparation and structural characterization of tetracoordinated tungsten(II) diazadiene complexes
Turki, Thouraya,Guerfel, Taha,Bouachir, Faouzi
, p. 1857 - 1861 (2007/10/03)
Reduction in situ of WCl4(MeCN)2 with zinc in the presence of diazadiene ligands 1b-f is reported and produces a series of diamagnetic complexes (DAD)WCl2 2b-f. All complexes were characterized by 1H, 13C NMR and IR spectroscopic data. The crystal structures of complexes 2b and 2e were solved by X-ray diffraction methods.