88787-16-0Relevant academic research and scientific papers
Modular synthesis of planar-chiral para-substituted paracyclophanes by double Suzuki coupling
Cakici, Murat,Braese, Stefan
, p. 6132 - 6135 (2013/01/15)
The first synthesis of enantiomerically pure 4,7-paracyclophane ditriflate starting from a quinone was reported. Using this molecule, mono-or dicoupling with boronic acids delivered enantiomerically pure arylparacyclophanes.
STERICALLY HINDERED CYCLOPHANES. PART I. SYNTHESIS OF PHENYL DERIVATIVES OF - AND 2,11-DITHIAPARACYCLOPHANES
Czuchajowski, Leszek,Zemanek, Aleksander
, p. 499 - 504 (2007/10/02)
Some phenyl derivatives of 2,11-dithiaparacyclophane, substituted in the aromatic rings, have been obtained by the high dilution technique.Their photolysis yielded respective derivatives of paracyclophane.In the latter, rotation of phenyl substituents has been found to be hindered.
