88790-04-9

Basic information

• Product Name: 2-Propanol, 1,1,1-trifluoro-3-(phenylthio)-
• CAS NO: 88790-04-9
• Molecular Formula: C9H9F3OS
• Molecular Weight: 222.231
• Mol File: 88790-04-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 289.3±40.0 °C(Predicted)
• Density: 1.32±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 2-Propanol, 1,1,1-trifluoro-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanol, 1,1,1-trifluoro-3-(phenylthio)-(88790-04-9)
• EPA Substance Registry System: 2-Propanol, 1,1,1-trifluoro-3-(phenylthio)-(88790-04-9)

Safety Data

• Hazardous Substances Data: 88790-04-9(Hazardous Substances Data)

Upstream product

• 359-41-1 1,1,1-trifluoro-2,3-epoxypropane 
• 108-98-5 thiophenol 
• 100-68-5 methyl-phenyl-thioether 
• 34509-09-6 1,1,1-trifluoro-3-(phenylthio)propan-2-one 

Downstream Products

• 88790-06-1 (1,2-Dibromo-3,3,3-trifluoro-propylsulfanyl)-benzene 
• 155444-61-4 phenyl β-(trifluoromethyl)vinyl sulfide 
• 110929-55-0 (S)-2-acetoxy-1,1,1-trifluoro-3-(phenylthio)propane 
• 110929-54-9 (2S)-(-)-3,3,3-Trifluoro-1-phenylthio-2-propanol 

Relevant articles and documents

Anodic methoxylation of 2-acyloxy-3,3,3-trifluoropropyl sulfides accompanying with [1,2]-rearrangement of the acyloxy group and anodic cyclization of 2-(t-butoxycarbonyl)oxy-3,3,3-trifluoropropyl sulfide

Anodic methoxylation of 2-acyloxy-3,3,3-trifluoropropyl sulfides was carried out in methanol containing Et3N-3HF as a supporting electrolyte and mediator using an undivided cell to provide the corresponding α-methoxylated products and unexpecte

Oxidation of Fluoroalkyl-Substituted Carbinols by the Dess-Martin Reagent

The efficient oxidation of mono-, di-, tri-, and perfluoroalkyl-substituted carbinols has been accommplished by the Dess-Martin periodinane oxidant.A variety of functional groups are compatible with the oxidation procedure.Monitoring the oxidation by 19F NMR indicated that a discreet periodinane intermediate is formed during the course of the reaction.Nonnucleophilic or sterically encumbered α-thiofluoro carbinols were readily oxidized; however, a nucleophilic α-thio-substituted trifluoromethyl carbinol was not.A tert-butyl alcohol modified periodinane oxidant was ultimately employed to achieve oxidation in this example.